Co-Ordination Polymers Based on Bis-Ligand Containing 4,6-Dichloro-N-Ethyl-N-Phenyl-1,3,5-Triazin-2-Amine and 5-Amino 8-Hydroxyquinoline Moieties

Co-Ordination Polymers Based on Bis-Ligand Containing 4,6-Dichloro-N-Ethyl-N-Phenyl-1,3,5-Triazin-2-Amine and 5-Amino 8-Hydroxyquinoline Moieties


Chaudhari AI, Chaudhari JA


Abstract

Co-ordination polymers containing a novel bis ligand namely 5,5'-(6-(ethyl(phenyl)amino)-1,3,5-triazine-2,4-diyl)bis(azanediyl)diquinolin-8-ol(TBQ-3) have been prepared with metal ion like Zn+2, Cu+2, Ni+2, Co+2 and Mn+2. The novel bis bidentate ligand (TBQ-3) is synthesized by condensation of 5-amino-8-hydroxyquinoline with 4,6-dichloro-N-ethyl-N-phenyl-1,3,5-triazin-2-amine in presence of base catalyst. All of these co-ordination polymers and parent ligand were characterized by elemental analysis, IR spectra and diffuse reflectance spectral studies for their structure determination. The thermal stability was evaluated by thermo gravimetric analyses (TGA). In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities. The microbicidal activity of all the samples have been monitored against plant pathogens.


Keywords

8-hydroxyquinoline, ligands(TBQ-3), Antibacterial and antifungal activities, Coordination polymers, IR, NMR, Reflectance spectra, TGA


Cite This Article

Chaudhari AI, Chaudhari JA, Co-Ordination Polymers Based on Bis-Ligand Containing 4,6-Dichloro-N-Ethyl-N-Phenyl-1,3,5-Triazin-2-Amine and 5-Amino 8-Hydroxyquinoline Moieties, International Journal for Pharmaceutical Research Scholars, 2013, 2(3), 122-128.

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